[Queen Mary University of London] University of Cambridge

Continuous heating transformation of bainite to austenite

J. R. Yang and H. K. D. H. Bhadeshia

Abstract

The transformation of a bainitic Fe-Mn-Si-C alloy into austenite has been studied using dilatometry, transmission electron microscopy and microanalytical techniques. The formation of austenite was investigated using two different starting microstructures, the first consisting of a mixture of bainitic ferrite and residual austenite, and the second of a mixture of tempered bainitic ferrite and carbides. Results from isothermal austenitization experiments confirm earlier work on a different alloy, that because of the incomplete reaction phenomenon associated with bainite growth, there is a large temperature hysteresis before the reverse transformation to austenite becomes possible. Continuous heating experiments revealed an identical austenitization behaviour for both initial microstructures when the heating rate utilized was small. This is because any residual austenite then tends to transform into pearlite or to decompose into ferrite and discrete particles of carbides before the sample reaches a temperature where austenite growth becomes thermodynamically feasible. Consequently, the two initial microstructures become identical by the time T-gamma is reached. At faster heating rates the residual austenite remains stable during heating and then commences to grow as the appropriate elevated temperature is reached. A slightly higher degree of superheating is found to be necessary in the absence of residual austenite in the starting microstructure, since austenite nucleation is then necessary prior to growth. Since the excess superheating is rather small, the results indicate that nucleation does not appear to be a major hurdle to the formation of austenite in the alloy studied.

This research investigates the kinetics of reaustenitisation within steel weld deposits, focusing on how different initial microstructures like bainite and acicular ferrite influence phase changes. The authors developed a thermodynamic model and used dilatometry to track how austenite grows through carbon diffusion across metal interfaces. By analyzing Time-Temperature-Transformation (TTT) curves, the study reveals that higher temperatures and specific structural surface areas significantly accelerate the rate of transformation. Additionally, the text examines continuous heating transformation, noting that chemical segregation in unhomogenised welds causes them to react at lower temperatures than more uniform samples. Ultimately, the work provides a quantitative framework to predict how heating rates and alloy compositions determine the final microscopic properties of welded steel.

Materials Science and Engineering A, Vol. A131, 1991, pp. 99-113.

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Study Guide: Reaustenitisation in Steel Weld Deposits

This study guide examines the kinetics of reaustenitisation in steel weld deposits, specifically focusing on the transformation from microstructures consisting of acicular ferrite plus austenite (αa) and bainite plus austenite (αb).

Part 1: Short Answer Quiz

  1. What is the primary objective of studying the kinetics of reaustenitisation in steel weld deposits?
  2. How does the starting microstructure influence the rate of transformation at a specific temperature?
  3. Describe the one-dimensional growth model used to predict austenite growth.
  4. What physical factor, represented by the symbol SV, explains why bainitic microstructures transform faster?

Part 2: Quiz Answer Key

  1. Knowledge of reaustenitisation kinetics is vital for predicting microstructural changes during transient temperature rises, such as those in laser or arc welds.
  2. While the final amount of transformation is the same, kinetics differ; acicular ferrite transformations are slower than bainite transformations, particularly at lower temperatures.
  3. The model assumes austenite growth occurs through the thickening of an existing layer via a planar γ/α interface, described by q = α1 t1/2.
  4. SV is the surface area of the γ/α boundary per unit volume. It is significantly larger for bainitic microstructures, providing more growth sites.

Part 4: Glossary of Key Terms

Term Definition
Acicular Ferrite (αa) A needle-like microstructure that serves as a starting point for reaustenitisation studies.
Bainite (αb) A plate-like microstructure with a high γ/α interface density.
Parabolic Rate Constant (α1) A value describing the rate at which the austenite layer thickens over time.



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