Queen Mary University of London University of Cambridge

Bainite to austenite transformation

Proceedings of an International Conference: Phase Transformations '87, Institute of Metals, London, Edited by G. W. Lorimer, 1988, pp. 203-206, by J. R. Yang and H.K.D.H. Bhadeshia

This research paper investigates the isothermal reaustenitisation process in steel, specifically examining how bainitic ferrite transforms back into austenite through diffusional growth. The study utilises a homogeneous alloy to analyse why this transformation occurs only after reaching specific thermal thresholds, as the initial bainite reaction typically halts before reaching equilibrium.

Through dilatometric experiments and theoretical modelling, the authors demonstrate that the degree of transformation increases with temperature until a fully austenitic state is achieved. The findings highlight that alloying element redistribution occurs during this phase change, moving toward a state of paraequilibrium at lower temperatures.

Ultimately, the work provides a theoretical framework to predict how the volume fraction of austenite evolves based on the carbon concentration and the phase diagram of the material.

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Jer Ren Yang and Harry Bhadeshia

Reaustenitisation from Bainite: A Study Guide

Based on the research by J.R. Yang and H.K.D. Bhadeshia regarding the diffusional growth of austenite in homogenised weld deposits.

Short-Answer Quiz

Instructions: Answer the following questions in 2–3 sentences based on the provided text.

1. What is the "incomplete reaction phenomenon" in the context of bainite transformation? The incomplete reaction phenomenon occurs when the bainite transformation ceases well before the residual austenite reaches its equilibrium carbon concentration. It stops specifically when the carbon concentration of the residual austenite reaches the To' curve, where the free energies of austenite and ferrite of the same composition are identical. 2. Why was the nucleation of austenite unnecessary in this specific study? The study utilised a starting microstructure that already contained a mixture of bainitic ferrite and residual austenite. Because austenite was already present in the initial state, the process of reaustenitisation only required the growth of existing austenite rather than the nucleation of new grains. 3. At what temperature does reaustenitisation first become detectable, and how does it progress? The first detectable growth of austenite occurs at an isothermal reaustenitisation temperature (Tγ) of 680°C. Initially, the transformation rate is rapid, but it decreases over time until the transformation eventually ceases at a point determined by the temperature. 4. What is the significance of the Tγ2 temperature point? The temperature Tγ2 (identified as 760°C for this alloy) represents the threshold above which the alloy can become fully austenitic. Below this temperature, reaustenitisation is incomplete, and the maximum volume fraction of austenite increases progressively from 680°C up to 760°C. 5. How does the carbon concentration of austenite (xγ) affect the driving force for reaustenitisation? Reaustenitisation is driven by the fact that the initial carbon concentration of the austenite (xγ) is higher than the equilibrium concentration (xAe3) at the reaustenitisation temperature. This concentration gradient provides the thermodynamic driving force for the ferrite-to-austenite (α → γ) transformation. 6. Explain the redistribution of substitutional alloying elements at low reaustenitisation temperatures. At low Tγ, microanalytical data indicates that substitutional alloying elements like manganese (mn) and nickel (ni) undergo redistribution during the transformation. This is evidenced by a partition coefficient (ki) that deviates from unity, signifying a move toward thermodynamic equilibrium. 7. What happens to the partitioning of alloying elements as the temperature increases? As the reaustenitisation temperature increases, the driving force also increases, causing the process to move toward paraequilibrium or negligible-partitioning-local equilibrium. In these states, the redistribution of substitutional alloying elements becomes minimal, and the partition coefficient approaches unity. 8. How was dilatometry used to interpret the results of the up-quench? Dilatometry measured length changes in the specimen; the vertical difference between the extrapolated length-temperature curve and the actual curve represents transformation progress. This allows researchers to calculate the extent of reaustenitisation occurring during the heating phase before reaching the isothermal temperature. 9. Under what conditions does cementite (θ) precipitate in this alloy? Cementite only precipitates if the mixture is tempered at 600°C for an extended period (e.g. two hours). At lower temperatures like 460°C for 30 minutes, no cementite is found, ensuring it does not interfere with the interpretation of reaustenitisation results. 10. What is the theoretical conclusion regarding the termination of the α → γ transformation? The theory predicts that the reverse transformation should cease when the carbon concentration of the growing austenite reaches the Ae3 curve. If this equilibrium concentration is reached before the alloy is fully austenitic, the transformation terminates, leaving a dual-phase microstructure.

Answer Key Summary

Refer to the Short-Answer Quiz section for detailed explanations. Key concepts include:

Essay Questions

Glossary of Key Terms

Term Definition
Ac1 Temperature The temperature at which austenite begins to form during heating.
Ae3 Curve The equilibrium phase boundary representing the limit of the austenite field in the presence of ferrite.
Bainitic Ferrite (αb) A plate-like phase of ferrite that forms from austenite at temperatures below the pearlite range.
Paraequilibrium A state in which only interstitial atoms (like carbon) redistribute, while substitutional elements (mn, ni) remain immobile.
Reaustenitisation The phase transformation process that converts a prior microstructure back into austenite.
Up-quench A rapid increase in temperature to a specific isothermal holding point.
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