Queen Mary University of London University of Cambridge

Evolution and cessation of the bainite transformation

Overview

Advanced real-time imaging and high-resolution diffraction techniques have fundamentally reshaped the scientific understanding of the bainite transformation in steel. Research utilising synchrotron X-rays and neutron diffraction has debunked the theory of precursor carbon fluctuations, proving that austenite remains chemically uniform until the transformation begins. These studies also reveal that bainitic ferrite possesses a tetragonal structure containing excess carbon, a finding that necessitates a revision of the standard $\text{Fe}\text{--}\text{C}$ phase diagram. Furthermore, atomic force and photoemission electron microscopy provide direct evidence that the growth of bainite is a rapid, displacive process occurring at speeds far beyond those possible by chemical diffusion. Technical analysis of acoustic emissions and thermal stability further clarifies how the specific morphology of retained austenite influences the mechanical durability and toughness of nanostructured steels. Ultimately, these diverse experimental methods confirm that the bainite reaction is a diffusionless transformation governed by precise thermodynamic limits.

Download publication: IOP Conf. Series: Materials Science and Engineering 1350 (2026) 012001

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